Porcelain stoneware is a high performance product with high wear
resistance, used for floor tiles in high traffic areas. The final product must
have a higher proportion of crystalline phase compared with the traditional
ceramic floor tiles in order to obtain a good resistance. For this reason the
chemical composition was chosen based on alkaline-earth oxides, which have the
ability to form compounds with high speed of crystallization. Theoretically
cordierite and mulltite have been chosen as the main mineralogical components
which were widely varied.
Samples were synthesized by pressing then heated (sintered) at 1200-13500C
with 2 hours plateau at maximum sintering temperature (thermal treatment
temperature).
On the thermally treated samples the variation of vitrification characteristics according to the thermal treatment temperature was determined. An appropriate behaviour to vitrification was observed for the samples with theoretical content of cordierite of 30-50%. The X-ray diffraction shows that at low temperatures (the cordierite is a major phase, but in low proportions magnesium spinel and mullite occur). The latter is a nonequilibrium compound that occurs as an intermediate phase in the formation of cordierite and entirely consumed over 1300°C. At temperature of 1300-1350°C remain crystalline only two components of equilibrium. Texture studies performed with electron microscopy revealed the presence of mullite as neddle form and cordierite as tabular form.